Divergent Reactivity of U(III) and U(II) Complexes with Organoazides via Isolable Diazenylimido Intermediates.

Deng, C.; Yang, Y.; Wang, Y.; Huang, W.*

Inorg. Chem. Front. 2024, Advanced Article.

 

 

 

 

Efficient Earth-Abundant Copper Photocatalysis Enabled by Metal–Arene Interaction.

Deng, C.; Huang, W.* 

Chem 2024, Advanced Article (Invited Preview).

 

 

f-Block Metal-Arene Interactions

Deng, C.; Wang, Y.; Huang, W.* 

Chin. J. Org. Chem. 2024, 44, Advanced Article.

 

 

 

Reduction of Thorium Tris(amido)arene Complexes: Reversible Double and Single C–C Couplings

Deng, C.; Liang, J.; Wang, Y.; Huang, W.* 

Inorg. Chem. 202463, 9676–9686.

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Neutral Inverse-Sandwich Rare-Earth Metal Complexes of the Benzene Tetraanion

Wang, Y.; Zhang, Y.; Liang, J.; Tan, B.; Deng, C.; Huang, W.* 

Chem. Sci202415, 8740–8749.

 

 

Topology-dependent synthesis, structures, and bonding interactions of uranium polyarene complexes.

Deng, C.; Xu, X.-C.; Sun, R.; Wang, Y.; Wang, B.-W.; Hu, H.-S.; Huang, W.*

Organometallics 2024, 43, 174–190.

 

 

 

A Combined Synthetic, Magnetic, and Theoretical Study on Enhancing Ligand-Field Axiality for Dy(III) Single–Molecule Magnets Supported by Ferrocene Diamide Ligands

Yang, K.; Sun, R.; Zhao, J.; Deng, C.; Wang, B.; Gao, S.; Huang, W.* 

Inorg. Chem. 202362, 9892–9903.

 

 

 

Accessing Five Oxidation States of Uranium in a Retained Ligand Framework

Deng, C.; Liang, J.; Sun, R.; Wang, Y.; Fu, P.-X.; Wang, B.-W.; Gao, S.; Huang, W.* 

Nat. Commun. 202314: 4657.

 

 

 

Two-Electron Oxidations at a Single Cerium Center

Wang, Y.; Liang, J.; Deng, C.; Sun, R.; Fu, P.-X.; Wang, B.-W.; Gao, S.; Huang, W.* 

J. Am. Chem. Soc2023145, 22466–22474.

This article is part of the themed collections:

 2024 JACS Covers

 

 

 

Multiply bound uranium–transition metal complexes featuring a cis-[M⇉U⇇M] core 

​Deng, C.; Huang, W.* 

Chinese J. Org. Chem. (有机化学) 202343, 3337–3338.

 

 

 

Trivalent Rare-Earth Metal Cyclic (Alkyl)(Amino)Carbene Complexes

Xiao, Y.; Liu, Z.; Liang, J.; Yang, K.; Huang, W.* 

Dalton Trans. 202251, 15873-15882.

 

 

 

 

5d on the Rise.

Huang, W.* (Invited Spotlight).

J. Phys. Chem. Lett. 2022, 13, 7437–7438.

 

 

 

 

Chapter 6. Organometallic Chemistry of Lanthanides.

Liddle, Stephen T.; Mills, David P.; Natrajan, Louise S., Editor(s),

The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications Huang, W.; Diaconescu, P. L.*

World Scientific, New Jersey, 2022; pp 209–309, LCCN 2021009805, ISBN 9781800610156.

 

 

 

 

Rare earth metal complexes supported by a tripodal tris(amido) ligand system featuring an arene anchor.

Xin, T.; Wang, X.; Yang, K.; Liang, J.; Huang, W.*

Inorg. Chem. 2021, 60, 15321–15329.

 

 

Homoleptic tris(6,6′-dimethyl-2,2′-bipyridine) rare earth metal complexes.

Xiao, Y.; Sun, R.; Liang, J.; Fang, Y.-H.; Liu, Z.; Jiang, S.-D.; Wang, B.-W.*; Gao, S.; Huang, W.*

Inorg. Chem. Front. 2021, 8, 2591–2602.

 

 

 

Chemistry of unusual oxidation states of actinides II. Molecular complexes.

Deng, C.; Su, Y.; Huang, W.*

Journal of Nuclear and Radiochemistry, 2021, 43, 1–20.

 

 

 

 

1.09 - Amide and Ketimide Metal Complexes.

In Comprehensive Coordination Chemistry III, Constable, E. C.; Parkin, G.; Que Jr, L., Editor(s).

Co, N. H.; Davis, A. R.; Deng, C.; Chantranuwathana, V.; Himel Rubin, E. R.; Subhan, M.; Huang, W.*; Diaconescu, P. L.*

Elsevier: Oxford, 2021; pp 178–296.

 

 

 

 

Arene-bridged dithorium complexes: Inverse sandwiches supported by a δ bonding interaction.

Yu, C.; Liang, J.; Deng, C.; Lefèvre, G.; Cantat, T.; Diaconescu, P. L.*; Huang, W.*

J. Am. Chem. Soc. 2020, 142, 21292–21297.

 

 

 

Distinct electronic structures and bonding interactions in inverse-sandwich Samarium and ytterbium biphenyl complexes.

Xiao, Y.; Zhao, X.-K.; Wu, T.; Miller, J. T.; Hu, H.-S.*; Li, J.; Huang, W.*; Diaconescu, P. L.*

Chem. Sci. 2021, 12, 227–238. 

 

 

Chemistry of unusual oxidation states of actinides I. Gas phase, solid state and aqueous solution.

Deng, C.; Su, Y.; Huang, W.*

Journal of Nuclear and Radiochemistry202042, 443–464.

 

 

Chemistry of non-traditional oxidation states of rare earth metals.

Wang, Y.; Huang, W.* (Special issue in memory of the 100th birthday of Prof. Guangxian Xu).

Sci. Sin. Chim. 2020, 50, 1504–1559.